**In the year
1817, Johann Wolfgang Döbereiner, a German chemist, tried to arrange the
elements with similar properties into groups. He identified some groups having
three elements each. So he called these groups ‘triads’.
**In 1866, John
Newlands, an English scientist, arranged the then known elements in the order
of increasing atomic masses. He started with the element having the lowest atomic
mass (hydrogen) and ended at thorium which was the 56th element. He
found that every eighth element had properties similar to that of the first. He
compared this to the octaves found in music. Therefore, he called it the ‘Law
of Octaves’.
**The main
credit for classifying elements goes to Dmitri Ivanovich Mendeléev, a Russian
chemist.
**On this
basis, Mendeléev formulated a Periodic Law, which states that ‘the properties of
elements are the periodic function of their atomic masses’.
**In 1913,
Henry Moseley showed that the atomic number of an element is a more fundamental
property than its atomic mass as described below.:: ‘Properties of elements are
a periodic function of their atomic number.’
**Atomic radius
decreases in moving from left to right along a period. This is due to an
increase in nuclear charge which tends to pull the electrons closer to the
nucleus and reduces the size of the atom.
**Metals like
Na and Mg are towards the left-hand side of the Periodic Table while the
non-metals like sulphur and chlorine are found on the right-hand side.
**Oxides of
metals are basic and that of non-metals are acidic in general.
**Mendel used a
number of contrasting visible characters of garden peas – round/wrinkled seeds,
tall/short plants, white/violet flowers and so on.
**Most human
chromosomes have a maternal and a paternal copy, and we have 22 such pairs. But
one pair, called the sex chromosomes, is odd in not always being a perfect
pair. Women have a perfect pair of sex chromosomes, both called X. But men have
a mismatched pair in which one is a normal-sized X while the other is a short
one called Y. So women are XX, while men are XY.
**A child who
inherits an X chromosome from her father will be a girl, and one who inherits a
Y chromosome from him will be a boy.
**The basic
structure of the limbs is similar though it has been modified to perform
different functions in various vertebrates. Such a homologous characteristic
helps to identify an evolutionary relationship between apparently different
species. The designs of the two wings(bats/birds), their structure and
components, are thus very different. They look similar because they have a
common use for flying, but their origins are not common. This makes them
analogous characteristics, rather than homologous characteristics.
**Alkaline
potassium permanganate or acidified potassium dichromate are oxidising alcohols
to acids, that is, adding oxygen to the starting material. Hence they are known
as oxidising agents.
**Unsaturated
hydrocarbons add hydrogen in the presence of catalysts such as palladium or
nickel to give saturated hydrocarbons. Catalysts are substances that cause a
reaction to occur or proceed at a different rate without the reaction itself
being affected. This reaction is commonly used in the hydrogenation of
vegetable oils using a nickel catalyst. VegeTable oils generally have long
unsaturated carbon chains while animal fats have saturated carbon chains.
Animal fats generally contain saturated fatty acids which are said to be
harmful for health.
**Saturated
hydrocarbons are fairly unreactive and are inert in the presence of most
reagents. However, in the presence of sunlight, chlorine is added to
hydrocarbons in a very fast reaction. Chlorine can replace the hydrogen atoms
one by one.
**Ethanol is
commonly called alcohol and is the active ingredient of all alcoholic drinks.
In addition, because it is a good solvent, it is also used in medicines such as
tincture iodine, cough syrups, and many tonics. Ethanol is also soluble in
water in all proportions. Consumption of small quantities of dilute ethanol
causes drunkenness. However, intake of even a small quantity of pure ethanol
(called absolute alcohol) can be lethal.
**Unlike
ethanol, intake of methanol in very small quantities can cause death. Methanol is
oxidised to methanal in the liver. Methanal reacts rapidly with the components
of cells. It causes the protoplasm to get coagulated, in much the same way an
egg is coagulated by cooking. Methanol also affects the optic nerve, causing
blindness.
**Sugarcane
plants are one of the most efficient convertors of sunlight into chemical energy.
Sugarcane juice can be used to prepare molasses which is fermented to give alcohol
(ethanol). Some countries now use alcohol as an additive in petrol since it is
a cleaner fuel which gives rise to only carbon dioxide and water on burning in
sufficient air (oxygen).
**The molecules
of soap are sodium or potassium salts of long-chain carboxylic acids. The
ionic-end of soap dissolves in water while the carbon chain dissolves in oil.
The soap molecules, thus form structures called micelles where one end of the
molecules is towards the oil droplet while the ionic-end faces outside. This
forms an emulsion in water.
**This is
caused by the reaction of soap with the calcium and magnesium salts, which
cause the hardness of water. This problem is overcome by using another class of
compounds called detergents as cleansing agents. Detergents are generally
ammonium or sulphonate salts of long chain carboxylic acids. The charged ends
of these compounds do not form insoluble precipitates with the calcium and
magnesium ions in hard water.
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